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Total Synthesis Study of Rauvomines A and B: Construction of the pentacyclic core structure

Abstract

A synthetic route has been developed for the core scaffold of Rauvomines, which possesses an abnormal sarpagine-type backbone without the C20-methylene substitution. The E-ring annulation was achieved by TiCl4-catalyzed Mukaiyama-Aldol reaction with a moderate yield of 70%.

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Supplementary files

Article information


Submitted
26 Dec 2019
Accepted
12 May 2020
First published
18 May 2020

Org. Chem. Front., 2020, Accepted Manuscript
Article type
Research Article

Total Synthesis Study of Rauvomines A and B: Construction of the pentacyclic core structure

B. Wu, Z. Jiang, J. Tang, Z. Gao, H. Liang, B. Tang, J. Chen and K. Lei, Org. Chem. Front., 2020, Accepted Manuscript , DOI: 10.1039/C9QO01531K

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