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Issue 6, 2020
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Cooperation of cerium oxide nanoparticles and soluble molecular catalysts for alcohol oxidation

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Abstract

Cerium oxide (ceria, CeO2−x) has been traditionally used as a catalyst support functionalized with metal nanoparticles or synthesized with metal dopants for a variety of applications ranging from catalytic converters to solid oxide fuel cells. In a departure from these typical heterogeneous motifs, we explore the interactions of nano-CeO2−x systems with organometallic oxidation catalysts in organic solvents. Ceria is used here both as an organically-capped colloid and as an uncapped insoluble nanopowder. Both the colloid and nanopowder act as terminal oxidants by accepting hydrogen atoms from a ruthenium Noyori–Ikariya hydride complex. To our knowledge, this is the first demonstration that CeO2−x can oxidize an organometallic hydride. Building on this concept, we show the uncapped CeO2−x powder also acts as the terminal acceptor in catalytic alcohol dehydrogenation reactions, utilizing iridium pyridine sulfonamide catalysts under anaerobic and aerobic conditions. The coupling of homogeneous oxidation catalysts with cerium oxide demonstrates the versatility of CeO2−x and a bridging of concepts in homogeneous and heterogeneous catalysis.

Graphical abstract: Cooperation of cerium oxide nanoparticles and soluble molecular catalysts for alcohol oxidation

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Supplementary files

Article information


Submitted
16 Dec 2019
Accepted
08 Feb 2020
First published
10 Feb 2020

Inorg. Chem. Front., 2020,7, 1386-1393
Article type
Research Article

Cooperation of cerium oxide nanoparticles and soluble molecular catalysts for alcohol oxidation

S. M. Laga, T. M. Townsend, A. R. O'Connor and J. M. Mayer, Inorg. Chem. Front., 2020, 7, 1386
DOI: 10.1039/C9QI01640F

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