CuI SNS triazole and imidazole pincers as electrocatalyst precursors for the production of solar fuels

Zachary J. Mast; Tessa H. T. Myren; Chloe G. Huntzinger; Taylor A. Stinson; Rami M. Kharbouch; Emilse M. Almanza; Samantha E. Zygmont; John R. Miecznikowski; Oana R. Luca

doi:10.1039/C9QI01510H

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Cu^I SNS triazole and imidazole pincers as electrocatalyst precursors for the production of solar fuels†

Zachary J. Mast,‡^a Tessa H. T. Myren,

‡^a Chloe G. Huntzinger,^a Taylor A. Stinson,^a Rami M. Kharbouch,^b Emilse M. Almanza,^b Samantha E. Zygmont,^b John R. Miecznikowski

*^b and Oana R. Luca

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and, University of Colorado Boulder, Boulder CO, 80300 USA
E-mail: oana.luca@colorado.edu

^b Department of Chemistry and Biochemistry, Fairfield University, Fairfield, CT, 06824 USA
E-mail: jmiecznikowski@fairfield.edu

Abstract

This work reports the first example of mono-nuclear Cu pincers with SNS ligation acting as electrocatalyst precursors for the electrochemical conversion of carbon dioxide to CO and H₂ in protic organic media.

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Article information

DOI: https://doi.org/10.1039/C9QI01510H
Article type: Research Article
Submitted: 21 Nov 2019
Accepted: 11 Jan 2020
First published: 21 Jan 2020

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Inorg. Chem. Front., 2020,7, 1012-1015

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Cu^I SNS triazole and imidazole pincers as electrocatalyst precursors for the production of solar fuels

Z. J. Mast, T. H. T. Myren, C. G. Huntzinger, T. A. Stinson, R. M. Kharbouch, E. M. Almanza, S. E. Zygmont, J. R. Miecznikowski and O. R. Luca, Inorg. Chem. Front., 2020, 7, 1012 DOI: 10.1039/C9QI01510H

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