Anna N. Philippova, Daria V. Vorobyeva, Florian Monnier and Sergey N. Osipov
Org. Biomol. Chem., 2020,18, 3274-3280
DOI:
10.1039/D0OB00580K,
Paper
An efficient synthetic approach to novel α-CF3-substituted E-dehydroornithine derivatives and their phosphorus analogues has been developed via the Cu(I)-catalyzed hydroamination of trifluoromethyl-containing α-allenyl-α-aminocarboxylates and α-allenyl-α-aminophosphonates with primary and secondary amines.