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Hierarchical self-assembly of helical coordination polymers and formation of a lamellar structure via the cooperativity of two-step Ag(i) coordination and π–π interactions

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Abstract

Hierarchical self-assembly from a V-shaped ligand 2,9-di(pyridin-4-yl)-1,10-phenanthroline (DPP) to an initial interlocked dimer, further to a coordination polymer with an alternate linear and interlocked helical configuration and finally to a lamellar structure with an undulating surface was precisely achieved in sequence via the cooperativity of two-step Ag (I) coordination and π–π interactions for the first time.

Graphical abstract: Hierarchical self-assembly of helical coordination polymers and formation of a lamellar structure via the cooperativity of two-step Ag(i) coordination and π–π interactions

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Article information


Submitted
10 Jan 2020
Accepted
28 Apr 2020
First published
29 Apr 2020

Nanoscale, 2020, Advance Article
Article type
Communication

Hierarchical self-assembly of helical coordination polymers and formation of a lamellar structure via the cooperativity of two-step Ag(I) coordination and π–π interactions

S. Wang, D. Bai, Y. Wang, J. Fu, J. Zhu and X. Fang, Nanoscale, 2020, Advance Article , DOI: 10.1039/D0NR00299B

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