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Tuning the morphology and redox behaviour by varying concentration of Fe in a CoNiFe Ternary Oxide Heterostructure for Hybrid Devices

Abstract

Incorporation of third transition metal cation (Fe – O) and its concentration on the configuration of cobalt nickel oxide has been studied. An attempt has been made to synthesize hierarchical porous cobalt–nickel–iron ternary oxide heterostructure arrays by a simple two-step approach, which is novel galvanostatic electrochemical technique followed by calcination. The synthesized ternary oxide heterostructure has been targeted as an electrode for the hybrid capacitor application due to their high redox potentials. A diaphragm cell was used for the electro-deposition of the ternary hydroxide at room temperature from a nitrate bath of the corresponding metal ions at pH of 2. A series of experiments were carried out with a fixed concentration of Co (30 g dm-3), and Ni (30 g dm-3) while varying concentrations of Fe (10, 20 and 30 g dm-3) at optimized pH of 2. The electrodeposited ternary metal hydroxides were calcined at an optimum temperature of 300 oC for 2 h to obtain the ternary oxide heterostructure. The formation of the ternary oxide heterostructure has been confirmed by X-ray diffraction analysis. The Field emission scanning electron microscopy images suggest the formation of a hierarchical nano flower architecture consisting of an interconnected flower petal with porous surface and spherical nano crystallites for various Fe concentrations. Transmission electron microscopy supports the formation of nano crystallites with the size of ~ 20 nm. The elemental analysis of the ternary oxides was carried out by Atomic Absorption Spectrophotometer, which suggests that all the materials contain Co, Ni, and Fe in various ratio. The result showed that with increase in Fe concentration from 10 to 30 g dm-3 with the fixed concentration of Co and Ni, the % of iron in the ternary composite increases with decrease in the concentration of Co and Ni. The increasing concentration of Fe in the metal oxide decreases the specific capacitance from 440 F/g to 272 F/g, indicating a significant difference in the observed redox processes. However, the cycling stability for both these samples showed excellent retention of over 92% after 1,000 cycles.

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Article information


Submitted
29 Mar 2020
Accepted
11 May 2020
First published
12 May 2020

New J. Chem., 2020, Accepted Manuscript
Article type
Paper

Tuning the morphology and redox behaviour by varying concentration of Fe in a CoNiFe Ternary Oxide Heterostructure for Hybrid Devices

A. Biswal, P. K. Panda, A. N. Acharya, B. Tripathy, F. Sh. Alenazey, Z. Jiang and M. Minakshi Sundaram, New J. Chem., 2020, Accepted Manuscript , DOI: 10.1039/D0NJ01486A

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