Issue 37, 2020

Incorporation of coinage metal–NHC complexes into heptaphosphide clusters

Abstract

Cu(I) and Au(I) ions, capped with an N-heterocyclic carbene (NHC), react with (TMS)3P7 (TMS = trimethyl-silyl) to afford an η4-coordinated anion [NHCDippCu–P7(TMS)] and a neutral trinuclear complex (NHCDippAu)3P7. Protecting the P7 cage with the TMS groups is instrumental in controlling the course of these reactions.

Graphical abstract: Incorporation of coinage metal–NHC complexes into heptaphosphide clusters

Supplementary files

Article information

Article type
Communication
Submitted
06 Sep 2020
Accepted
08 Sep 2020
First published
09 Sep 2020

Dalton Trans., 2020,49, 12955-12959

Author version available

Incorporation of coinage metal–NHC complexes into heptaphosphide clusters

M. Jo, J. Li, A. Dragulescu-Andrasi, A. Yu. Rogachev and M. Shatruk, Dalton Trans., 2020, 49, 12955 DOI: 10.1039/D0DT03119D

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