Issue 37, 2020
From the journal:

Dalton Transactions

{VMo9O31[RC(CH2O)3]}6−: the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates†

Di Qu,a   Xiaoting Liu,a   Fengxue Duan,a   Rong Xue,*b   Bao Li ORCID logo *a  and  Lixin Wu ORCID logo a  

* Corresponding authors

a State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China
E-mail: libao@jlu.edu.cn

b National Analytical Research Center of Electrochemistry and Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, P. R. China
E-mail: xuerong@ciac.ac.cn

Abstract

Three trivacant polyoxomolybdates were constructed, presenting the first class of triol ligand covalently-decorated Keggin-type clusters through C–O–Mo bonds. The introduction of the organic component enhanced the stability of the cluster in the solid state with the leaving of active sites at the lacunary position.

Graphical abstract: {VMo9O31[RC(CH2O)3]}6−: the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates

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Article information

DOI
https://doi.org/10.1039/D0DT02506B
Article type
Communication
Submitted
16 Jul 2020
Accepted
27 Aug 2020
First published
27 Aug 2020

Dalton Trans., 2020,49, 12950-12954

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{VMo9O31[RC(CH2O)3]}6−: the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates

D. Qu, X. Liu, F. Duan, R. Xue, B. Li and L. Wu, Dalton Trans., 2020, 49, 12950 DOI: 10.1039/D0DT02506B

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