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Issue 20, 2020
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Combination of solid-state NMR and 1H NMR relaxometry for the study of intercalated saponite clays with the macrocyclic derivatives of Gd(iii) and Y(iii)

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Abstract

Positively charged Gd(III) and Y(III) complexes were intercalated in the gallery of a synthetic saponite. A combination of solid-state NMR and 1H NMR relaxometric investigations has been employed to characterize these hybrid systems. This enabled us to gain atomic level insights into the local environment of the chelates and to evaluate the interactions of the metal species with the co-intercalated water molecules.

Graphical abstract: Combination of solid-state NMR and 1H NMR relaxometry for the study of intercalated saponite clays with the macrocyclic derivatives of Gd(iii) and Y(iii)

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Article information


Submitted
25 Mar 2020
Accepted
21 Apr 2020
First published
21 Apr 2020

Dalton Trans., 2020,49, 6566-6571
Article type
Communication

Combination of solid-state NMR and 1H NMR relaxometry for the study of intercalated saponite clays with the macrocyclic derivatives of Gd(III) and Y(III)

D. Lalli, S. Marchesi, F. Carniato, C. Bisio, L. Tei, L. Marchese and M. Botta, Dalton Trans., 2020, 49, 6566
DOI: 10.1039/D0DT01125H

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