A new approach to the synthesis of trinuclear gold(I) imidazolate complexes and their silver(I)-induced photoluminescence behavior

Javier Ruiz; Daniel Sol; María A. Mateo; Marilín Vivanco; Rosana Badía-Laiño

doi:10.1039/D0DT01246G

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A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior†

Javier Ruiz,

*^a Daniel Sol,^a María A. Mateo,^a Marilín Vivanco^a and Rosana Badía-Laiño^b

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* Corresponding authors

^a Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, 33006 Oviedo, Spain
E-mail: Jruiz@uniovi.es

^b Departamento de Química Física y Analítica, Facultad de Química, Universidad de Oviedo, 33006 Oviedo, Spain

Abstract

New trinuclear gold(I) N-arylimidazolate cluster complexes have been synthesized from cationic [Au(CNR)₂]⁺ isocyanide complexes and their structure and photoluminescence behavior have been compared with those of their 1-methylimidazolate counterpart. A drastic change in their photophysical properties was observed upon coordination of the Ag⁺ cation.

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Article information

DOI: https://doi.org/10.1039/D0DT01246G
Article type: Communication
Submitted: 03 Apr 2020
Accepted: 17 Apr 2020
First published: 17 Apr 2020

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Dalton Trans., 2020,49, 6561-6565

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A new approach to the synthesis of trinuclear gold(I) imidazolate complexes and their silver(I)-induced photoluminescence behavior

J. Ruiz, D. Sol, M. A. Mateo, M. Vivanco and R. Badía-Laiño, Dalton Trans., 2020, 49, 6561 DOI: 10.1039/D0DT01246G

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Dalton Transactions

A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior†

Abstract

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A new approach to the synthesis of trinuclear gold(I) imidazolate complexes and their silver(I)-induced photoluminescence behavior

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