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Incorporation of a Nitrogen-Rich Energetic Ligand in a {YbIII2} Complex Exhibiting Slow Relaxation of the Magnetization Under an Applied Field.

Abstract

Though often used as the precursor in energetic materials research and organic synthesis, 3,6-dihydrazinyl-1,2,4,5-tetrazine (dhtz) has not been previously explored in coordination chemistry. Herein, we present the first crystalline coordination compound with dhtz, [Yb2(dhtz)(fod)6] (fod- = 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionate). This compound exhibits Single-Molecule Magnet behaviour under an applied magnetic field, and mJ states were resolved through luminescence studies.

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Supplementary files

Article information


Submitted
24 Feb 2020
Accepted
28 Apr 2020
First published
28 Apr 2020

Dalton Trans., 2020, Accepted Manuscript
Article type
Communication

Incorporation of a Nitrogen-Rich Energetic Ligand in a {YbIII2} Complex Exhibiting Slow Relaxation of the Magnetization Under an Applied Field.

P. Richardson, D. A. Galico, J. S. Ovens, F. A. Sigoli and M. Murugesu, Dalton Trans., 2020, Accepted Manuscript , DOI: 10.1039/D0DT00696C

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