The first amino acid bound manganese–calcium clusters: a {[MnIII3Ca]2} methylalanine complex, and a [MnIII6Ca] trigonal prism

Thomais G. Tziotzi; Evangelos K. Andreou; Eirini Tzanetou; Dimitris A. Kalofolias; Daniel J. Cutler; Marek Weselski; Milosz Siczek; Tadeusz Lis; Euan K. Brechin; Constantinos J. Milios

doi:10.1039/D0DT01916J

The first amino acid bound manganese–calcium clusters: a {[Mn ^III₃Ca]₂} methylalanine complex, and a [Mn ^III₆Ca] trigonal prism†

Thomais G. Tziotzi,^a Evangelos K. Andreou,^a Eirini Tzanetou,^a Dimitris A. Kalofolias,

^a Daniel J. Cutler,^b Marek Weselski,^c Milosz Siczek,

^c Tadeusz Lis,^c Euan K. Brechin

^b and Constantinos J. Milios

*^a

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* Corresponding authors

^a Department of Chemistry, The University of Crete, Voutes, Herakleion, Greece
E-mail: komil@uoc.gr

^b EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, EH9 3FJ, UK

^c Faculty of Chemistry, University of Wroclaw, 50-283 Wroclaw, Poland

Abstract

An amino acid containing octanuclear heterometallic {[Mn^III₃Ca]₂} cluster has been synthesized, alongside a structurally-related trigonal prismatic [Mn^III₆Ca]²⁺ cage.

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The first amino acid bound manganese–calcium clusters: a {[Mn ^III₃Ca]₂} methylalanine complex, and a [Mn ^III₆Ca] trigonal prism†

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The first amino acid bound manganese–calcium clusters: a {[Mn^III₃Ca]₂} methylalanine complex, and a [Mn^III₆Ca] trigonal prism

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