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Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands

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Abstract

The ability of alkali metal complexes featuring functionalized BINOL-derived ligands to catalyze ketone hydroboration reactions was explored. The reduced products were formed in excellent yields and with variable enantioselectivities dependent upon the nature of the ligand and the alkali metal cation.

Graphical abstract: Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands

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Article information


Submitted
22 Nov 2019
Accepted
22 Jan 2020
First published
10 Feb 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands

D. Willcox, J. L. Carden, A. J. Ruddy, P. D. Newman and R. L. Melen, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT00232A

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