Jump to main content
Jump to site search

Deoxofluorination of graphite oxide with sulfur tetrafluoride

Author affiliations


In this study, deoxofluorination of graphite oxide (GO) using sulfur tetrafluoride (SF4) at a temperature below the decomposition temperature of GO (∼200 °C) was investigated for the first time with and without HF catalysis. At 25 °C, the reaction proceeds only at high SF4 pressures (≥8 atm) when not catalyzed by HF and at 1 atm SF4 under the catalysis of HF. The degree of fluorination increases at higher temperatures and SF4 pressures. Hydroxy and carbonyl groups are replaced by fluorine following this reaction, and SF4 and SOF2 are introduced into the product, while the epoxy groups do not react. SF4 and SOF2 in the products are removed by washing with water. The obtained product is less hygroscopic than pristine GO owing to the hydrophobicity of the fluorine atom. The interlayer separation of the product is increased after deoxofluorination despite the smaller size of fluorine than the sizes of the oxygen-containing functional groups. When compared with direct fluorination using elemental fluorine, deoxofluorination using SF4 has the advantages of high reactivity with hydroxy groups and the preservation of the carbon skeleton, and the reaction results in the formation of graphite oxyfluoride.

Graphical abstract: Deoxofluorination of graphite oxide with sulfur tetrafluoride

Back to tab navigation

Supplementary files

Publication details

The article was received on 24 Sep 2019, accepted on 01 Nov 2019 and first published on 01 Nov 2019

Article type: Paper
DOI: 10.1039/C9DT03782A
Dalton Trans., 2020, Advance Article

  •   Request permissions

    Deoxofluorination of graphite oxide with sulfur tetrafluoride

    H. Yamamoto, K. Matsumoto, Y. Matsuo, Y. Sato and R. Hagiwara, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT03782A

Search articles by author