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Issue 3, 2020
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Relating structural disorder and melting in complex mixed ligand zeolitic imidazolate framework glasses

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Abstract

We report the formation of zeolitic imidazolate framework glasses incorporating three organic linkers, from their corresponding novel crystalline structures [Zn(Im2−xybImxmbImy)]. Structure–property relationships between chemical compositions and thermal properties are analysed, in addition to the effect on the nanoscale porosity of the glasses formed. A probabilistic model is used to explain melting and the glass transition temperatures of the obtained glasses and link to the nanoscale structural disorder of their crystalline starting structures.

Graphical abstract: Relating structural disorder and melting in complex mixed ligand zeolitic imidazolate framework glasses

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Article information


Submitted
03 Sep 2019
Accepted
12 Dec 2019
First published
12 Dec 2019

Dalton Trans., 2020,49, 850-857
Article type
Paper

Relating structural disorder and melting in complex mixed ligand zeolitic imidazolate framework glasses

M. L. Ríos Gómez, G. I. Lampronti, Y. Yang, J. C. Mauro and T. D. Bennett, Dalton Trans., 2020, 49, 850
DOI: 10.1039/C9DT03559A

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