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Domino Lignin Depolymerization and Reconnection to Complex Molecules Mediated by Boryl Radicals

Abstract

Chemical degradation of lignin has attracted increasing interest due to its potential in producing chemicals from renewable ressources. Herein we present a new transition metal free degradation procedure utilizing DDQ-oxidation and boryl radical mediated degradation, followed by reconnection of the monomer intermediate to a new dimer in a domino process. Our results include the selective degradation of oxidized β-O-4 model compounds by boryl radical initiated by catalytic amount of 4-(4-pyridinyl)-benzonitrile and bispinacolborane B2(pin)2 as well as its application to organosolv-lignin. This sequential procedure expands the toolbox for lignin degradation from simple depolymerization to high-value products by incorporating a bond forming transformations within the process, and also provides a new transition-metal free method for the construction of 1,6-diketone fragments.

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Article information


Accepted
24 Mar 2020
First published
26 Mar 2020

Catal. Sci. Technol., 2020, Accepted Manuscript
Article type
Paper

Domino Lignin Depolymerization and Reconnection to Complex Molecules Mediated by Boryl Radicals

L. Hong, A. Spielmeyer, J. Pfeiffer and H. A. A. Wegner, Catal. Sci. Technol., 2020, Accepted Manuscript , DOI: 10.1039/D0CY00558D

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