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Issue 40, 2020
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A comprehensive approach for the characterization of porous polymers using 13C and 15N dynamic nuclear polarization NMR spectroscopy

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Abstract

Most porous polymers are notoriously hard to characterize due to their amorphous and completely insoluble nature. On the other hand, they are an interesting class of materials for sorption, catalytic, and electrode applications, thus they warrant in-depth studies. In this contribution, we elaborate on the possibilities that dynamic nuclear polarization offers towards the investigation of the structure of porous polymers. We discuss the advantages and disadvantages of this technique in the investigation of model polymers.

Graphical abstract: A comprehensive approach for the characterization of porous polymers using 13C and 15N dynamic nuclear polarization NMR spectroscopy

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Article information


Submitted
28 Jul 2020
Accepted
16 Sep 2020
First published
21 Sep 2020

Phys. Chem. Chem. Phys., 2020,22, 23307-23314
Article type
Paper

A comprehensive approach for the characterization of porous polymers using 13C and 15N dynamic nuclear polarization NMR spectroscopy

S. Grätz, M. de Olivera Junior, T. Gutmann and L. Borchardt, Phys. Chem. Chem. Phys., 2020, 22, 23307
DOI: 10.1039/D0CP04010J

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