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C-H···S Interaction Exhibits all the Characteristics of Conventional Hydrogen Bonds

Abstract

This is a tale of a pair of hydrogen bond donor and acceptor, namely CH donor and Sulphur acceptor, none of which is a conventional hydrogen bond participant. Sulfur (S) being less electronegative (2.58) compared to its first row analogue, oxygen (3.44), has not been considered as a potential HB acceptor for a long time. The CH···Y (Y= HB acceptor) interaction has its own history of exhibiting omnidirectional shifts in the CH stretching frequency upon complex formation. Therefore, systematic investigation of the CH···S interaction was the primary goal of the work presented here. Together with gas-phase vibrational spectroscopy and ab initio quantum chemical calculations the nature and strength of C-H···S hydrogen bond (HB) has been investigated in the complexes of 1,2,4,5-tetracyanobenzene (TCNB) with various sulfur containing solvents. Despite the unconventional nature of both HB donor and HB acceptor (C-H and S, respectively), it was found that the C-H···S hydrogen bond exhibits all the characteristics of the conventional hydrogen bond. The binding strength of the C-H···S H-bond in these complexes was found to be comparable to that of the conventional hydrogen bonds. The unusual stabilities of these HBs have been mainly attributed to the attractive dispersion interaction.

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Article information


Submitted
19 Mar 2020
Accepted
22 May 2020
First published
22 May 2020

Phys. Chem. Chem. Phys., 2020, Accepted Manuscript
Article type
Paper

C-H···S Interaction Exhibits all the Characteristics of Conventional Hydrogen Bonds

S. Ghosh, P. Chopra and S. Wategaonkar, Phys. Chem. Chem. Phys., 2020, Accepted Manuscript , DOI: 10.1039/D0CP01508C

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