Issue 19, 2020
From the journal:

CrystEngComm

An X-shaped cyano–carbonyl interaction on the polar surface of (cyanoacetyl)hydrazones†

Zhenfeng Zhang ORCID logo a  

a School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Henan Key Laboratory of Organic Functional Molecule and Drug Innovation, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Xinxiang, Henan 453007, China
E-mail: zzf@htu.cn
Fax: +86 373 3326336
Tel: +86 373 3326336

Abstract

An X-shaped C[triple bond, length as m-dash]N⋯C[double bond, length as m-dash]O interaction, which plays a critical role in dictating the molecule conformation and crystal packing patterns, has been found to occur on the polar surface of (cyanoacetyl)hydrazones, and is rationalized by density functional theory calculations. MEPs, NBOs and topological analyses offer further support for the interaction.

Graphical abstract: An X-shaped cyano–carbonyl interaction on the polar surface of (cyanoacetyl)hydrazones

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0CE00359J
Article type
Communication
Submitted
08 Mar 2020
Accepted
15 Apr 2020
First published
15 Apr 2020

CrystEngComm, 2020,22, 3274-3278

Permissions

Request permissions

An X-shaped cyano–carbonyl interaction on the polar surface of (cyanoacetyl)hydrazones

Z. Zhang, CrystEngComm, 2020, 22, 3274 DOI: 10.1039/D0CE00359J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements