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Issue 85, 2020
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A phosphine-free iron complex-catalyzed synthesis of cycloalkanes via the borrowing hydrogen strategy

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Abstract

Herein we report a diaminocyclopentadienone iron tricarbonyl complex catalyzed synthesis of substituted cyclopentane, cyclohexane and cycloheptane compounds using the borrowing hydrogen strategy in the presence of various substituted primary and secondary 1,n diols as alkylating reagents. Deuterium labeling experiments confirm that the diols were the hydride source in this cascade process.

Graphical abstract: A phosphine-free iron complex-catalyzed synthesis of cycloalkanes via the borrowing hydrogen strategy

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Article information


Submitted
28 Aug 2020
Accepted
18 Sep 2020
First published
23 Sep 2020

Chem. Commun., 2020,56, 12909-12912
Article type
Communication

A phosphine-free iron complex-catalyzed synthesis of cycloalkanes via the borrowing hydrogen strategy

L. Bettoni, S. Gaillard and J. Renaud, Chem. Commun., 2020, 56, 12909 DOI: 10.1039/D0CC05840H

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