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Arylation of aryllithiums with S-arylphenothiazinium ions for biaryl synthesis

Abstract

Aryllithiums are one of the most common and important aryl nucleophiles; nevertheless, methods for arylation of aryllithums to produce biaryls have been limited. Herein, we report arylation of aryllithiums with S-arylphenothiazinium ions through selective ligand coupling of intermediary sulfuranes. Various unsymmetrical biaryls could be obtained without transition-metal catalysis.

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Article information


Submitted
28 Aug 2020
Accepted
13 Oct 2020
First published
13 Oct 2020

This article is Open Access

Chem. Commun., 2020, Accepted Manuscript
Article type
Communication

Arylation of aryllithiums with S-arylphenothiazinium ions for biaryl synthesis

T. Morofuji, T. Yoshida, R. Tsutsumi, M. Yamanaka and N. Kano, Chem. Commun., 2020, Accepted Manuscript , DOI: 10.1039/D0CC05830K

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