Syntheses of a new tripodal alane/tris(phosphine) ligand (AlP3) based on 2-(diisopropylphosphino)pyrrole, and AlP3-supported Ni complexes are reported. The central tris(pyrrolyl)aluminum moiety acts as a stronger Lewis acid towards Ni than other related group 13 element-centered tripodal ligands, as demonstrated by the binding of H2 to Ni and the ease of reduction.
Q. Lai, M. N. Cosio and O. V. Ozerov, Chem. Commun., 2020, 56, 14845 DOI: 10.1039/D0CC05452F
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