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Issue 94, 2020
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Probing the peripheral role of amines in photo- and electrocatalytic H2 production by molecular cobalt complexes

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Abstract

The incorporation of amine functionality in the periphery of a synthetic cobaloxime core induces excellent photo-(TON 180) and electrocatalytic H2 production (TOF 4330 s−1) in aqueous solution. The primary amine group displays a superior influence on the catalysis compared to a secondary amine group with an analogous cobaloxime template.

Graphical abstract: Probing the peripheral role of amines in photo- and electrocatalytic H2 production by molecular cobalt complexes

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Article information


Submitted
27 Aug 2020
Accepted
02 Nov 2020
First published
02 Nov 2020

Chem. Commun., 2020,56, 14841-14844
Article type
Communication

Probing the peripheral role of amines in photo- and electrocatalytic H2 production by molecular cobalt complexes

D. Dolui, A. Q. Mir and A. Dutta, Chem. Commun., 2020, 56, 14841
DOI: 10.1039/D0CC05786J

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