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Issue 85, 2020
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Hydrophobicity-driven folding and seeded polymerization of cystine-based dimeric diamides in aqueous media

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Abstract

Seeded supramolecular polymerization of cystine-based dimeric diamides with aromatic substituents at the C- and N-termini was achieved in aqueous media. Theoretical and spectroscopic studies reveal that the terminal groups play crucial roles in slowing spontaneous assembly through formation of a folded conformation and guiding molecular alignment in the aggregated state.

Graphical abstract: Hydrophobicity-driven folding and seeded polymerization of cystine-based dimeric diamides in aqueous media

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Article information


Submitted
01 Aug 2020
Accepted
15 Sep 2020
First published
19 Sep 2020

Chem. Commun., 2020,56, 12901-12904
Article type
Communication

Hydrophobicity-driven folding and seeded polymerization of cystine-based dimeric diamides in aqueous media

N. Fukaya, S. Ogi, M. Kawashiro and S. Yamaguchi, Chem. Commun., 2020, 56, 12901
DOI: 10.1039/D0CC05255H

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