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Abstract | Cited by

A mild copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids is described. This three-component protocol provides a straightforward approach to the remote keto-functionalized 1,1-diarylmethane derivatives. A radical pathway initiated by C–C bond cleavage is proposed for this tandem reaction.

Graphical abstract: Copper-catalyzed alkylarylation of vinylarenes with cycloalkylsilyl peroxides and boronic acids

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