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Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) electrophile

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Abstract

H–B(dan) was demonstrated to serve as a B(dan) electrophile, despite its highly diminished boron-Lewis acidity, leading to direct and transition metal-free approach to R–B(dan) of high synthetic utility upon treatment with Grignard reagents. Iterative cross-coupling of 5-bromo-2-pyridyl–B(dan), synthesized by the present method, was also achieved.

Graphical abstract: Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) electrophile

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Article information


Submitted
09 Apr 2020
Accepted
30 Apr 2020
First published
30 Apr 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) electrophile

J. Li, M. Seki, S. Kamio and H. Yoshida, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02560G

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