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Dipyridinoarsole: a new class of stable and modifiable heteroatom-bridged bipyridines

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Abstract

Herein, we report our experimental and computational investigations on a stable and modifiable As-bridged dipyridinoheterole, dipyridinoarsole. Oxidation of the arsenic atom changes the frontier orbital energies and quaternization of nitrogen atoms produces electrochromic materials. Dipyridinoarsole is suitable for practical applications due to its superior stability compared to its phosphole analogues.

Graphical abstract: Dipyridinoarsole: a new class of stable and modifiable heteroatom-bridged bipyridines

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Article information


Submitted
02 Apr 2020
Accepted
11 May 2020
First published
11 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Dipyridinoarsole: a new class of stable and modifiable heteroatom-bridged bipyridines

T. Fujii, S. Tanaka, S. Hayashi, H. Imoto and K. Naka, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02389B

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