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Chiral stimuli-responsive metallo-supramolecular assembly induced by CuII/CuI redox change

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Abstract

We investigated the selective formation of homoleptic and heteroleptic metal complexes controlled by means of the chiral molecular instruction of the ligand and the coordination geometry of the metal. Our results showed that chiral self-recognition or self-discrimination may be induced by the CuI/CuII redox transition using cyclic voltammetry. The further use of chiral ditopic ligands led to metallo-supramolecular copolymers with stimuli-responsive controlled arrangement.

Graphical abstract: Chiral stimuli-responsive metallo-supramolecular assembly induced by CuII/CuI redox change

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Article information


Submitted
05 Mar 2020
Accepted
24 Jun 2020
First published
25 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Chiral stimuli-responsive metallo-supramolecular assembly induced by CuII/CuI redox change

M. Marinova, A. Bonnefont, T. Achard, A. Maisse-François and S. Bellemin-Laponnaz, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01716G

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