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Issue 44, 2020
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Ruthenium-catalyzed synthesis of vinylamides at low acetylene pressure

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Abstract

The reaction of cyclic amides with acetylene under low pressure, using ruthenium-phosphine catalysts, afforded a broad variety of N-vinylated amides including (azabicyclic) lactams, oxazolidinones, benzoisoxazolones, isoindolinones, quinoxalinones, oxazinanones, cyclic urea derivatives (imidazolidinones), nucleobases (thymine), amino acid anhydrides and thiazolidinone.

Graphical abstract: Ruthenium-catalyzed synthesis of vinylamides at low acetylene pressure

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Article information


Submitted
27 Feb 2020
Accepted
20 Apr 2020
First published
21 Apr 2020

Chem. Commun., 2020,56, 5977-5980
Article type
Communication

Ruthenium-catalyzed synthesis of vinylamides at low acetylene pressure

E. Semina, P. Tuzina, F. Bienewald, A. S. K. Hashmi and T. Schaub, Chem. Commun., 2020, 56, 5977
DOI: 10.1039/D0CC01533D

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