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Selective metalation of phenol-type proligands for preparative organometallic chemistry

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Abstract

The selective C-metalation of phenol ester derived proligands is a readily applicable addition to state-of-the-art protocols toward cyclometalated structures, in particular of the base metals. The approach is demonstrated by the ortho-nickelation of a 1,10-phenanthroline based strong-field ligand platform that is a sought-after motif in the field of base-metal photochemistry.

Graphical abstract: Selective metalation of phenol-type proligands for preparative organometallic chemistry

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Article information


Submitted
17 Feb 2020
Accepted
28 Feb 2020
First published
02 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Selective metalation of phenol-type proligands for preparative organometallic chemistry

A. Berkefeld, M. Fröhlich, M. Kordan, G. Hörner and H. Schubert, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01254H

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