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Sequence-directed dynamic covalent assembly of base-4-encoded oligomers

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Abstract

As an information-bearing biomacromolecule, DNA is encoded in base-4, where each residue site can be occupied by any one of four nucleobases. Mimicking the information dense, sequence-selective hybridization of DNA, we demonstrate two orthogonal dynamic covalent interactions to effect the selective assembly of molecular ladders and grids from base-4-encoded oligo(peptoid)s.

Graphical abstract: Sequence-directed dynamic covalent assembly of base-4-encoded oligomers

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Article information


Submitted
11 Feb 2020
Accepted
24 Jun 2020
First published
24 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Sequence-directed dynamic covalent assembly of base-4-encoded oligomers

S. C. Leguizamon, M. F. Dunn and T. F. Scott, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01083A

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