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Enhancing switchable dielectric property for crystalline supramolecular rotor compounds by adding polar components

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Abstract

Two new compounds were obtained by assembling the [(2-methoxy-5-nitro-anilinium)(18-crown-6)]+ cation with non-polar PF6 and polar SO3CF3 anions, respectively. Benefiting from its polar anion, the SO3CF3 compound reveals a more significant dielectric switching behaviour during phase transition, demonstrating an effective strategy to enhance the dielectric property by adding polar components.

Graphical abstract: Enhancing switchable dielectric property for crystalline supramolecular rotor compounds by adding polar components

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Article information


Submitted
08 Feb 2020
Accepted
05 Mar 2020
First published
05 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Enhancing switchable dielectric property for crystalline supramolecular rotor compounds by adding polar components

R. Huang, X. Chen, Z. Xiao, D. Liu, W. Zhang and X. Chen, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC01026J

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