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Bi- and Poly(carbyne) functionalised Polycyclic Aromatics

Abstract

Complexes where a central polyaromatic ring system is substituted with one to four tungsten carbynes have been prepared by Pd0/AuI-mediated coupling between a tungsten stannylcarbyne and aryl halides. This strategy enables preparation of complexes with one to three carbynes substituted onto a single phenyl ring, the first anthracenyl mono- and bis- carbynes, and a tetra(carbyne) complex constructed about a central pyrene ring system

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Article information


Accepted
10 Feb 2020
First published
10 Feb 2020

Chem. Commun., 2020, Accepted Manuscript
Article type
Communication

Bi- and Poly(carbyne) functionalised Polycyclic Aromatics

A. Hill, B. Frogley and A. Seitz, Chem. Commun., 2020, Accepted Manuscript , DOI: 10.1039/D0CC00786B

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