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Bi- and poly(carbyne) functionalised polycyclic aromatics

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Abstract

Complexes where a central polyaromatic ring system is substituted with one to four tungsten carbynes have been prepared by Pd0/AuI-mediated coupling between a tungsten stannylcarbyne and aryl halides. This strategy enables preparation of complexes with one to three carbynes substituted onto a single phenyl ring, the first anthracenyl mono- and bis-carbynes, and a tetra(carbyne) complex constructed about a central pyrene ring system.

Graphical abstract: Bi- and poly(carbyne) functionalised polycyclic aromatics

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Article information


Submitted
31 Jan 2020
Accepted
10 Feb 2020
First published
10 Feb 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Bi- and poly(carbyne) functionalised polycyclic aromatics

B. J. Frogley, A. F. Hill and A. Seitz, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC00786B

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