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NaH-mediated direct C–H arylation in the presence of 1,10-phenanthroline

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Abstract

Transition-metal-free coupling of haloarenes with unactivated arenes has been developed in the presence of NaH and 1,10-phenanthroline. Various haloarenes bearing methyl, methoxy, halogen (fluoride, chloride, and bromide), cyano, trifluoromethyl, ester, and amide groups can be cross-coupled with unactivated arenes, or heteroarenes in this reaction.

Graphical abstract: NaH-mediated direct C–H arylation in the presence of 1,10-phenanthroline

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Article information


Submitted
28 Jan 2020
Accepted
17 Jun 2020
First published
17 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

NaH-mediated direct C–H arylation in the presence of 1,10-phenanthroline

K. Nozawa-Kumada, Y. Iwakawa, S. Onuma, M. Shigeno and Y. Kondo, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC00730G

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