Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.



The intercalation of 1,10-phenanthroline into layered NiPS3via iron dopant seeding

Author affiliations

Abstract

Using 2% percent of iron dopants as reaction active sites yields a series of single crystals of 1,10-phenanthroline intercalated NiPS3, via a solution reaction with aniline chloride, not possible by a direct reaction. Experimental magnetic susceptibility measurements demonstrate that 1,10-phenanthroline intercalation suppresses the anti-ferromagnetism ordering at around 150 K in Fe0.02Ni0.98PS3, and gives rise to a ferrimagnetic phase transition at a temperature around 75 K. An intercalation mechanism is proposed for the reaction, and this dopant seeding method provides a new approach for intercalation into layered materials.

Graphical abstract: The intercalation of 1,10-phenanthroline into layered NiPS3 via iron dopant seeding

Back to tab navigation

Supplementary files

Article information


Submitted
23 Jan 2020
Accepted
17 Mar 2020
First published
18 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

The intercalation of 1,10-phenanthroline into layered NiPS3 via iron dopant seeding

X. Ma, L. Zhang, C. Xu, Q. Dong, R. I. Walton, Z. Li, H. Shi, G. Chen, J. Hu, J. Li and H. Yang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC00636J

Social activity

Search articles by author

Spotlight

Advertisements