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Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal

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Abstract

We report herein three pentagonal-bipyramidal holmium(III) complexes sharing the formula [Ho(L)2(py)5][BPh4], where L is the alkoxide ligand. For L = (OSi(CH3)3), a record energy barrier for magnetization reversal (Ueff = 715(6) K) was revealed, which is due to the pure state transition of mJ = |±8〉 → mJ = |±7〉 → mJ = |±6〉.

Graphical abstract: Understanding a pentagonal-bipyramidal holmium(iii) complex with a record energy barrier for magnetisation reversal

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Article information


Submitted
18 Jan 2020
Accepted
02 Mar 2020
First published
02 Mar 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Understanding a pentagonal-bipyramidal holmium(III) complex with a record energy barrier for magnetisation reversal

Y. Ma, Y. Zhai, Y. Ding, T. Han and Y. Zheng, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC00500B

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