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Issue 43, 2020
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Palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones for the synthesis of trans cycloalkanols through dynamic kinetic resolution under acidic conditions

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Abstract

The first efficient palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones has been described through dynamic kinetic resolution under acidic conditions, providing a facile access to chiral trans cycloalkanol derivatives with excellent enantioselectivities.

Graphical abstract: Palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones for the synthesis of trans cycloalkanols through dynamic kinetic resolution under acidic conditions

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Article information


Submitted
18 Jan 2020
Accepted
18 Apr 2020
First published
20 Apr 2020

Chem. Commun., 2020,56, 5815-5818
Article type
Communication

Palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones for the synthesis of trans cycloalkanols through dynamic kinetic resolution under acidic conditions

X. Li, Z. Zhao, M. Chen, B. Wu, H. Wang, C. Yu and Y. Zhou, Chem. Commun., 2020, 56, 5815
DOI: 10.1039/D0CC00480D

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