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Interfacial synthesis of crystalline two-dimensional cyano-graphdiyne

Abstract

A well-defined crystalline cyano-functionalized graphdiyne (CN-GDY) is synthesized at liquid/liquid interface through alkyne-alkyne coupling reaction. The configurations and nanostructures of CN-GDY were well characterized by TEM, SEM, AFM, XPS, and Raman spectroscopy. HR-TEM and selected area electron diffraction (SAED) in combination of structure simulation firmly revealed a 9-fold stacking mode for CN-GDY.

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Supplementary files

Article information


Submitted
11 Dec 2019
Accepted
10 Feb 2020
First published
10 Feb 2020

Chem. Commun., 2020, Accepted Manuscript
Article type
Communication

Interfacial synthesis of crystalline two-dimensional cyano-graphdiyne

Z. Zhang, C. Wu, Q. Pan, F. Shao, Q. Sun, S. Chen, Z. Li and Y. Zhao, Chem. Commun., 2020, Accepted Manuscript , DOI: 10.1039/C9CC09617E

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