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Low temperature dissociation of CO on manganese promoted cobalt(poly)

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Abstract

We observe that metallic manganese alloyed with polycrystalline cobalt promotes the dissociation of CO. Increasing coverages of Mn on Co facillitate stronger molecular CO binding energies and stronger C(ad) + O(ad) binding energies. These findings show the role of metallic manganese in promoting model Co Fischer–Tropsch catalysis.

Graphical abstract: Low temperature dissociation of CO on manganese promoted cobalt(poly)

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Article information


Submitted
08 Oct 2019
Accepted
31 Jan 2020
First published
31 Jan 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Low temperature dissociation of CO on manganese promoted cobalt(poly)

R. A. Ciufo, S. Han, M. E. Floto, G. Henkelman and C. B. Mullins, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC07722G

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