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Thiocyanate complexes of the lanthanides, Am and Cm

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Abstract

The synthesis and single crystal structures of Am(III) and Cm(III) thiocyanate complexes are reported along with an isostructural series of lanthanide thiocyanate complexes. Because the complexes are isostructural, a comparative study of the metal–thiocyanate bonds was conducted using Raman spectroscopy indicating very similar and electrostatic metal–ligand interactions.

Graphical abstract: Thiocyanate complexes of the lanthanides, Am and Cm

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Article information


Submitted
27 Sep 2019
Accepted
13 Jan 2020
First published
04 Feb 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Thiocyanate complexes of the lanthanides, Am and Cm

R. E. Wilson, T. J. Carter, M. Autillo and S. Stegman, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC07612C

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