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Identifying C2H4N4 structural isomers using fs-laser induced breakdown spectroscopy

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Abstract

Four C2H4N4 structural isomers are investigated with fs laser-induced breakdown spectroscopy. Plasma emissions, C I, Hα, the CN violet system (B2Σ+–X2Σ+, Δν = 0 sequence) and C2 swan system (d3Πg–a3Πu, Δν = 0 sequence) are measured. The temporal evolution of the characteristic emission intensity is obtained for each emission and their lifetimes are calculated. The lifetimes of the molecular emissions are much longer than those of the atomic emissions. Characteristic emission intensities and lifetime are correlated with the molecular structures of the four isomers to a certain extent. Plasma temperature is extracted by fitting the spectrum of the CN violet system, B2Σ+–X2Σ+; Δν = 0 sequence, and is weakly correlated with the molecular structures of the four isomers. Using the characteristic emission intensities as input, principal component analysis (PCA) and artificial neural network (ANN) analysis are performed and the individual isomers can be well identified with PCA or ANN.

Graphical abstract: Identifying C2H4N4 structural isomers using fs-laser induced breakdown spectroscopy

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Article information


Submitted
08 Aug 2020
Accepted
18 Aug 2020
First published
19 Aug 2020

Analyst, 2020, Advance Article
Article type
Paper

Identifying C2H4N4 structural isomers using fs-laser induced breakdown spectroscopy

Y. L. Zhao, G. D. Lai, G. G. Li, Y. L. Shang and J. C. Shi, Analyst, 2020, Advance Article , DOI: 10.1039/D0AN01593H

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