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Issue 43, 2020
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A new heterometallic pivalate {Fe8Cd} complex as an example of unusual “ferric wheel” molecular self-assembly

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Abstract

The interaction of the pivalate complexes of iron(III), [Fe3O(Piv)6(H2O)3]·HPiv, and cadmium(II), [Cd(Piv)2], in Et2O resulted in one more type of “ferric wheel” family complex, namely [Fe8(Piv)16{Cd(Piv)2}(μ-OH)8]·Et2O (1). The complex is an octanuclear iron(III) wheel with a {Cd(Piv)2} moiety asymmetrically incorporated into the ring.

Graphical abstract: A new heterometallic pivalate {Fe8Cd} complex as an example of unusual “ferric wheel” molecular self-assembly

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Article information


Submitted
08 Sep 2020
Accepted
06 Oct 2020
First published
07 Oct 2020

Dalton Trans., 2020,49, 15175-15179
Article type
Communication

A new heterometallic pivalate {Fe8Cd} complex as an example of unusual “ferric wheel” molecular self-assembly

I. A. Lutsenko, M. A. Kiskin, K. A. Lysenko, E. M. Zueva, N. N. Efimov, E. A. Ugolkova, Y. V. Maksimov, V. K. Imshennik, M. M. Petrova, A. A. Sidorov and I. L. Eremenko, Dalton Trans., 2020, 49, 15175
DOI: 10.1039/D0DT03142A

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