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Rh(I)-Catalyzed intramolecular [3 + 2] cycloaddition reactions of yne-vinylidenecyclopropanes

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Abstract

A cationic Rh(I) complex-catalyzed intramolecular [3 + 2] cycloaddition reaction of newly developed yne-vinylidenecyclopropanes (VDCPs) has been established, affording an efficient synthesis of fused [6.5]-bicyclic structures in moderate to good yields under mild conditions. Moreover, the reaction exhibits a broad substrate scope along with good functional group tolerance.

Graphical abstract: Rh(i)-Catalyzed intramolecular [3 + 2] cycloaddition reactions of yne-vinylidenecyclopropanes

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Publication details

The article was received on 08 Mar 2019, accepted on 02 Apr 2019 and first published on 03 Apr 2019


Article type: Research Article
DOI: 10.1039/C9QO00343F
Citation: Org. Chem. Front., 2019, Advance Article

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    Rh(I)-Catalyzed intramolecular [3 + 2] cycloaddition reactions of yne-vinylidenecyclopropanes

    K. Rui and M. Shi, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C9QO00343F

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