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Scandium-catalyzed electrophilic alkene difunctionalization: regioselective synthesis of thiosulfone derivatives

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Abstract

A scandium(III)-catalyzed electrophilic alkene difunctionalization reaction with the synergistic formation of two C–S bonds has been developed. This reaction features a broad substrate scope, simple procedures, 100% atom economy, and a reversed regioselectivity compared to previously studied alkene sulfonylation methods.

Graphical abstract: Scandium-catalyzed electrophilic alkene difunctionalization: regioselective synthesis of thiosulfone derivatives

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Publication details

The article was received on 28 Jan 2019, accepted on 28 Mar 2019 and first published on 29 Mar 2019


Article type: Research Article
DOI: 10.1039/C9QO00138G
Citation: Org. Chem. Front., 2019, Advance Article

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    Scandium-catalyzed electrophilic alkene difunctionalization: regioselective synthesis of thiosulfone derivatives

    S. Huang, H. Li, T. Xie, F. Wei, C. Tung and Z. Xu, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C9QO00138G

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