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Circularly polarised luminescence from planar-chiral Phanephos/Tb(iii)(hfa)3 hybrid luminophores

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Abstract

Planar-chiral Phanephos, containing the coordinatable P(III), formed P(III)/Tb(III)(hfa)3 hybrid luminophores that successfully emitted characteristic circularly polarised luminescence (CPL) due to 5D47F5 transitions in solution. On the other hand, BINAP, containing P(III)[double bond, length as m-dash]O as axially chiral ligand, exhibited no detectable CPL with Tb(III)(hfa)3.

Graphical abstract: Circularly polarised luminescence from planar-chiral Phanephos/Tb(iii)(hfa)3 hybrid luminophores

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Publication details

The article was received on 13 Jul 2019, accepted on 23 Oct 2019 and first published on 24 Oct 2019


Article type: Paper
DOI: 10.1039/C9PP00296K
Photochem. Photobiol. Sci., 2019, Advance Article

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    Circularly polarised luminescence from planar-chiral Phanephos/Tb(III)(hfa)3 hybrid luminophores

    A. Taniguchi, N. Hara, M. Shizuma, N. Tajima, M. Fujiki and Y. Imai, Photochem. Photobiol. Sci., 2019, Advance Article , DOI: 10.1039/C9PP00296K

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