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Chiral benzazaboroles as catalysts for enantioselective sulfonylation of cis-1,2-diols

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Abstract

A newly developed benzazaborole smoothly catalyzed the enantioselective sulfonylation of cis-1,2-diols. Using a chiral benzazaborole/NMI co-catalyst system, various sulfonate esters were prepared in high yields with good enantioselectivities.

Graphical abstract: Chiral benzazaboroles as catalysts for enantioselective sulfonylation of cis-1,2-diols

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Publication details

The article was received on 26 Dec 2018, accepted on 13 Mar 2019 and first published on 14 Mar 2019


Article type: Paper
DOI: 10.1039/C8OB03205J
Citation: Org. Biomol. Chem., 2019, Advance Article

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    Chiral benzazaboroles as catalysts for enantioselective sulfonylation of cis-1,2-diols

    S. Kuwano, Y. Hosaka and T. Arai, Org. Biomol. Chem., 2019, Advance Article , DOI: 10.1039/C8OB03205J

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