Issue 24, 2019
From the journal:

New Journal of Chemistry

Metal-free thioesterification of amides generating acyl thioesters†

Qun Wang,a   Long Liu, ORCID logo b   Jianyu Dong,*c   Zhibin Tianb  and  Tieqiao Chen ORCID logo *ab  

* Corresponding authors

a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
E-mail: chentieqiao@hnu.edu.cn

b Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, College of Materials and Chemical Engineering, Hainan University, Haikou, China

c Department of Educational Science, Hunan First Normal University, Changsha 410205, China
E-mail: djyustc@hotmail.com

Abstract

A base-initiated thioesterification of amides with various thiols is reported. This reaction can take place efficiently under metal-free and air-atmospheric conditions, and provides a facile and practically useful approach to the synthesis of valuable acyl thioesters.

Graphical abstract: Metal-free thioesterification of amides generating acyl thioesters

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Article information

DOI
https://doi.org/10.1039/C9NJ01748H
Article type
Paper
Submitted
05 Apr 2019
Accepted
15 May 2019
First published
16 May 2019

New J. Chem., 2019,43, 9384-9388

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Metal-free thioesterification of amides generating acyl thioesters

Q. Wang, L. Liu, J. Dong, Z. Tian and T. Chen, New J. Chem., 2019, 43, 9384 DOI: 10.1039/C9NJ01748H

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