Issue 16, 2019

Enhanced catalytic activity of cobalt nanoparticles encapsulated with an N-doped porous carbon shell derived from hollow ZIF-8 for efficient synthesis of nitriles from primary alcohols in water

Abstract

A cobalt catalyst derived from a unique core–shell structure based on hollow ZIF-8 and ZIF-67 (ZIF-67@ZIF-8) is prepared, which exhibits excellent catalytic efficiency for the synthesis of nitriles from alcohols in water under mild conditions (1 atm O2, 50 °C) owing to its large BET surface area, high pore volume, high basicity and hydrophilicity.

Graphical abstract: Enhanced catalytic activity of cobalt nanoparticles encapsulated with an N-doped porous carbon shell derived from hollow ZIF-8 for efficient synthesis of nitriles from primary alcohols in water

Supplementary files

Article information

Article type
Communication
Submitted
06 Jun 2019
Accepted
25 Jul 2019
First published
26 Jul 2019

Green Chem., 2019,21, 4334-4340

Enhanced catalytic activity of cobalt nanoparticles encapsulated with an N-doped porous carbon shell derived from hollow ZIF-8 for efficient synthesis of nitriles from primary alcohols in water

K. Sun, J. Sun, G. Lu and C. Cai, Green Chem., 2019, 21, 4334 DOI: 10.1039/C9GC01893J

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