Jump to main content
Jump to site search

Issue 2, 2019
Previous Article Next Article

A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Author affiliations

Abstract

The [PdCl4]2− palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(II)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck–Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity.

Graphical abstract: A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Back to tab navigation

Supplementary files

Article information


Submitted
14 Oct 2018
Accepted
13 Dec 2018
First published
21 Dec 2018

Green Chem., 2019,21, 355-360
Article type
Paper

A tailored polymeric cationic tag–anionic Pd(II) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

H. Mahmoudi, F. Valentini, F. Ferlin, L. A. Bivona, I. Anastasiou, L. Fusaro, C. Aprile, A. Marrocchi and L. Vaccaro, Green Chem., 2019, 21, 355
DOI: 10.1039/C8GC03228A

Social activity

Search articles by author

Spotlight

Advertisements